Photocatalytic water splitting has continuously been a hot academic topic since Fujishima and Hondas work in hydrogen production from water using a TiO 2 electrode [].Over the past decades, metal sulfides [] and chalcogenides [] have attracted broad interest from scientists engaged in photocatalysis.Of those compounds, cadmium sulfide (CdS) is an attractive semiconductor . Dofia JM, Herrero J. Theoretical Characterization of Triangular CdS Nanocrystals: A Tight-Binding Approach. Nozik, A. J., Williams, F., Nenadovic, M. T., Rajh, T. & Micic, O.I. Cadmium sulfide is a chemical compound that has the formula CdS. Article Ali J, Ali N, Wang L, Waseem H, Pan G. Revisiting the mechanistic pathways for bacterial mediated synthesis of noble metal nanoparticles. 1, pp. NH3was added in the above solution to precipitate out Cd(OH)2then it is dissolved in excess of NH3to form Cd[NH3]4SO4. The effect of using sodium thiosulfate as an additional sulfur precursor was also investigated (combined milling). M. D. Rao and G. Pennathur, Green synthesis and characterization of cadmium sulphide nanoparticles from Chlamydomonas reinhardtii and their application as photocatalysts, Materials Research Bulletin, vol. The wide band gap, low absorption loss, compact crystallographic cell structure and electronic affinity makes CdS is a promising optoelectronic device for making solar cell CISe and InP .Thin films of CdS have received widespread attention in the direction of other device applications . View via Publisher Save to Library 2005 Jul 18;44(29):4554-7. doi: 10.1002/anie.200500830. Cadmium, a rare but widely dispersed element, is found naturally in the environment. Grasso G, Zane D, Dragone R. Microbial nanotechnology: challenges and prospects for green biocatalytic synthesis of nanoscale materials for sensoristic and biomedical applications. 2021 Apr 26;11(5):1117. doi: 10.3390/nano11051117. Researchers have reported production of nanostructures using an electron beam [22]. In recent years, controlling the morphology and size of nanomaterials has been a crucial issue in nanoscience research due to their fundamental shape- and size-dependent properties and significant applications. The diffraction pattern of the melted portion corresponds to cubic phase CdS with a lattice constant of a = 5.82 , which is similar to the diffraction pattern prior to the melting of the nanorods. 263, 41864192 (1988). 167, pp. Green MA, Dunlop ED, Levi DH, Hohl-Ebinger J, Yoshita M, Ho-Baillie AWY. 145151, 2014. The XRD analysis revealed that the as-synthesized product is a crystalline CdS with a cubic zinc blend crystal structure. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. K. Venugopal, H. A. PLoS ONE. 2011;153:12532. It is yellow in color and is a semiconductor of electricity. Wang, Y. UYP1 and their application as photosensitizer in solar cells. Y. Wang, G. Meng, L. Zhang, C. Liang, and J. Zhang, Catalytic growth of large-scale single crystal CdS nanowires by physical evaporation and their photoluminescence, Chemistry of Materials, vol. 545550, 2016. Total loading time: 0 Grill, E., Winnacker, E. L. & Zenk, M. H. Science 230, 674676 (1985). Meyer, M., Walberg, C., Kurihara, K. & Fendler, J. H. J. chem. The solution used was sulfide/polysulfide (S2/Sn2) and it was prepared with 1M Na2S, 0.1M S and 0.1M NaOH dissolved in ultrapure water. Small. Bruna N, Collao B, Tello A, Caravantes P, Daz-Silva N, Monrs JP, et al. 18, pp. Amarelle V, Carrasco V, Fabiano E. The hidden life of Antarctic rocks. Structures with either one, two or all three dimensions on the nanometer scale are of particular interest in solid state physics6. Friedmann EI. Nies DH. Abstract. This letter shows how, by correct orientation of the crystalline axes, mixed or pure modes of vibration can be obtained. Melting point: 609.92 degrees Fahrenheit (321.07 degrees Celsius) Boiling point: 1,412.6 F (767 C) Number of isotopes . Phys. Kiessling F, Mertens ME, Grimm J, Lammers T. Nanoparticles for imaging: top or flop? Energy dispersive X-ray spectroscopy (EDX) analysis confirmed that biosynthesized CdS QDs were composed of 51.1% cadmium and 48.9% sulfide, while the amorphous matrix was mostly composed of organic matter with presence of carbon, oxygen, and other elements (Fig. PubMed Matheyarasu, R. In recent years, the morphology effect of semiconductor nanocrystallites on their physical properties has aroused extensive attention [12,13]. 2019;159:1825. 2018;41:131933. The powder XRD pattern of the as-prepared CdS nanorods is shown in Figure Figure1.1. 40, no. Peptide Gelators to Template Inorganic Nanoparticle Formation. Cadmium sulfide quantum dots (CdS QDs) are widely used in solar cells, light emitting diodes, photocatalysis, and biological imaging because of their unique optical and electrical properties. Chem. J Biol Inorg Chem. Cadmium Sulfide Nanocrystal Biosynthesis. rdenes-Aenishanslins N, Anziani-Ostuni G, Quezada CP, Espinoza-Gonzlez R, Bravo D, Prez-Donoso JM. Thayalan, Wanethon 5, pp. Pedobacter sp. 2008 Jul;4(7):951-5. doi: 10.1002/smll.200700787. 6473, 2017. Colloids Surf B Biointerfaces. 156, no. CAS CAS R. Sanghi and P. Verma, A facile green extracellular biosynthesis of CdS nanoparticles by immobilized fungus, Chemical Engineering Journal, vol. Cadmium sulfide is one of the cutting-edge materials of current optoelectronic technology. 2010 Feb;2(2):168-87. doi: 10.1039/b9nr00415g. Dopant-Induced Formation of Branched CdS Nanocrystals. However, it is more common as an impurity substituent in the similarly structured ores of zinc, wurtzite, and sphalerite . Biological synthesis of CdS/CdSe core/shell nanoparticles and its application in quantum dot sensitized solar cells. 70, no. The properties of cadmium sulphide buffer layer in solar cells have been identified by several authors as the major determinant of the efficiency of the cells and CBD is the most convenient . Peng ZA, Peng X. Mechanisms of the Shape Evolution of CdSe Nanocrystals. 1986;124:55760. Part of 71, no. https://doi.org/10.1186/s12934-021-01531-4, DOI: https://doi.org/10.1186/s12934-021-01531-4. b, Corresponding. 1422030209), the Innovation Team Program of NORINCO Group (Grant No. CdS nanoparticles were successfully synthesized using cadmium acetate and sodium sulfide as Cd and S precursors, respectively. 2021 Feb 2;7(1):14. doi: 10.3390/gels7010014. You may switch to Article in classic view. Photocatalytic activities of both CdS . Sugano, S., Nishina, Y. The ePub format uses eBook readers, which have several "ease of reading" features https://doi.org/10.1038/338596a0. 1991;173:697703. 2, no. Lipopolysaccharides are present on the outer membrane of gram-negative bacteria, and they hinder the entrance of macromolecules and other hydrophilic molecules. 5566, 2015. Morphological variations in cadmium sulfide nanocrystals without phase transformation. Rather, K. Rajagopal et al., Synthesis of silver nanoparticles (Ag NPs) for anticancer activities (MCF 7 breast and A549 lung cell lines) of the crude extract of Syzygium aromaticum, Journal of Photochemistry and Photobiology B: Biology, vol. Article PDF Available. VA collaborated with the experimental work regarding strain isolation and characterization. I. Sandoval-Crdenas, M. Gmez-Ramrez, and N. G. Rojas-Avelizapa, Use of a sulfur waste for biosynthesis of cadmium sulfide quantum dots with Fusarium oxysporum f. sp. Cadmium sulfide is an inorganic compound with the chemical formula CdS. envir. 1, no. The 0.16 M CdSO4 solution was first added to 7.5 M NH4OH solution under constant stirring. Mubarak Ali et al. Epitaxial Growth of Size-Quantized Cadmium Sulfide Crystals Under Afrachidic Acid Monolayers. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. The sensitization of the TiO2 film was done by direct absorption of the CdS QDs. 11, pp. 509512, 2009. These were obtained to examine the morphological variations and diffraction patterns at different stages. The absorption peaks for nanorods are located at 496 nm, which is blue-shifted from the bulk band gap value of CdS (517 nm) due to the quantum confinement effect. 2017;66:683705. rdenes-Aenishanslins NA, Saona LA, Durn-Toro VM, Monrs JP, Bravo DM, Prez-Donoso JM. Perspectives on the physical chemistry of semiconductor nanocrystals. Naidu, R. In this study, we prepared CdS QDs by liquid phase synthesis under ambient room temperature and atmospheric pressure using sodium alkyl sulfonate, CdCl2, and Na2S as capping agent, cadmium, and sulfur sources respectively. Ind Eng Chem Res. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. C. T. Dameron, B. R. Smith, and D. R. Winge, Glutathione-coated cadmium- sulfide crystallites in Candida glabrata, The Journal of Biological Chemistry, vol. Federal government websites often end in .gov or .mil. Phase at room temperature: Solid. & Herron, N. J. phys. A. Azam, A. S. Ahmed, M. Oves, M. S. Khan, S. S. Habib, and A. Memic, Antimicrobial activity of metal oxide nanoparticles against Gram-positive and Gram-negative bacteria: a comparative study, International Journal of Nanomedicine, vol. View all Google Scholar citations This phenomenon is very unique in CdS nanorods and could be potentially applicable for smart materials. Z. R. Khan, M. Zulfequar, and M. S. Khan, Chemical synthesis of CdS nanoparticles and their optical and dielectric studies, Journal of Materials Science, vol. These nanoparticles have antimicrobial and anticancer capabilities, and it could be a powerful tool for other biotechnological applications such as fluorescent microscopy and signal transduction. Environ Pollut. Brasier, Martin J Microbiol Methods. Production of cadmium sulfide quantum dots by the lithobiontic Antarctic strain, https://doi.org/10.1186/s12934-021-01531-4, http://creativecommons.org/licenses/by/4.0/, http://creativecommons.org/publicdomain/zero/1.0/. The authors declare that they have no competing interests. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate. Please choose 6872, 2010. S. Rajeshkumar, M. Ponnanikajamideen, C. Malarkodi, M. Malini, and G. Annadurai, Microbe-mediated synthesis of antimicrobial semiconductor nanoparticles by marine bacteria, Journal of Nanostructure in Chemistry, vol. Phys. 4-5, pp. Careers. 328334, 2016. Soc. The CdS nanorods of Zn-blend cubic crystal structure were prepared by a chemical bath method. These PL emissions indicate that after light absorption in the CdS nanorods, the photogenerated electron/hole pair was trapped, with emission at 467 nm upon their recombination. Cadmium is strongly redox-controlled, and normally concentrated in anoxic marine sediments or epigenetic mineralization involving organic matter. . 424427, 2018. Biochem., Tokyo 96, 13751379 (1984). Biological synthesis of fluorescent nanoparticles by cadmium and tellurite resistant Antarctic bacteria: exploring novel natural nanofactories. J. Virkutyte and R. S. Varma, Green synthesis of metal nanoparticles: biodegradable polymers and enzymes in stabilization and surface functionalization, Chemical Science, vol. 2016;55:1123544. Nature (Nature) 41, pp. The history of CdS, more recent advances in the chemistry and synthesis of CdS nanostructures, and their application as nanoscale devices in diverse technology areas from electronics to targeted drug delivery is described. Disclaimer. Henglein, A. in Topics in Current Chemistry 143, 113181 (Springer, Berlin, 1988). X-ray data indicate that, at this small size, the CdS structure differs from that of bulk CdS and tends towards a six-coordinate rock-salt structure. Chem. Beyond labels: a review of the application of quantum dots as integrated components of assays, bioprobes, and biosensors utilizing optical transduction. J. phys. 1999;51:73050. Appl Environ Microbiol. R. Bhambure, M. Bule, N. Shaligram, M. Kamat, and R. Singhal, Extracellular biosynthesis of gold nanoparticles using Aspergillus niger - its characterization and stability, Chemical Engineering and Technology, vol. hasContentIssue true, Copyright The Mineralogical Society of Great Britain and Ireland 2014. 2015;32:309. 94, no. 1, no. 4, pp. IEEE J. quan. Please enable it to take advantage of the complete set of features! A. Rzigalinski and J. S. Strobl, Cadmium-containing nanoparticles: perspectives on pharmacology and toxicology of quantum dots, Toxicology and Applied Pharmacology, vol. 63, pp. UYP1 strain grown in R2A medium, with or without 1mM cysteine. Project supported by the Equipment Pre-research Fund under the Equipment Development Department (EDD) of Chinas Central Military Commission (CMC) (Grant No. BioNanotechnology and Microbiology Laboratory, Center for Bioinformatics and Integrative Biology, Facultad de Ciencias Biolgicas, Universidad Andres Bello, Av. CAS 228244, 2011. Since Klabunde and his coworkers demonstrated that the reactive of metal oxide nanoparticles displays strong antibacterial activity [54], there has been great interest in exploring the use of inorganic nanoparticles as antibacterial materials. Microb Cell Fact 20, 41 (2021). Int Microbiol. 16S ribosomal DNA amplification for phylogenetic study. Commun. phys. 2009 Apr 14;10(6):879-82. doi: 10.1002/cphc.200800827. The solar cells were tested by pouring the polysulphide electrolyte between the two electrodes. 29, pp. 23, pp. 886891, 2009. 9, pp. Overall representative TEM images shown in Figure Figure2a2a revealed that the length of the CdS nanorods is in the range of 2 to 3 m. Development and applications of the heterostructures synthesis based on CdS nanowires. D. Wang, Z. Lin, T. Wang et al., Where does the toxicity of metal oxide nanoparticles come from: the nanoparticles, the ions, or a combination of both? Journal of Hazardous Materials, vol. 1, pp. 3339, 2017. A. S. Bhadwal, R. M. Tripathi, R. K. Gupta, N. Kumar, R. P. Singh, and A. Shrivastav, Biogenic synthesis and photocatalytic activity of CdS nanoparticles, RSC Advances, vol. 356363, 2014. Received 2010 Dec 22; Accepted 2011 Jun 14. Small. 50, no. Mbene, K. Chem., Japan 36, 5973 (1986). Davidheiser-Kroll, Brett Mater Lett. Content may require purchase if you do not have access. Provided by the Springer Nature SharedIt content-sharing initiative. The SAED pattern shown in Figure 3b,e corresponds to zinc blend CdS with high crystallinity. Render date: 2023-03-18T09:59:23.119Z & Thomas, J. K. Chem. The cadmium-peptide complexes of tomato contained predominantly peptides of n 3, n 4, and n 5. spectroscopic analyses indicated that the tomato cadmium-sulfide-peptide complex contained CdS crystallite core particles smaller than 2.0 nanometers in diameter. The samples were characterized by XRD, Raman spectroscopy, XPS, UV-Vis spectroscopy, PL spectroscopy, DLS, and TEM. To obtain Measurements were performed using sun intensity irradiance (~100mWcm2 and AM1.5) as light source. 65, no. Microorganisms. 90, 33933399 (1986). Metal homeostasis and resistance in bacteria. However the Stoer Group was deposited in a terrestrial environment, including lacustrine deposits of shale. Scanning electron microscopy revealed the presence of spherical particles measuring . Radiology. A TEM sample was then prepared by putting a minute amount of CdS nanorods powder on a carbon-coated copper grid, without dispersing powder in the solvent. Repblica 239, 8370146, Santiago, PC, Chile, V. Carrasco,S. Lagos-Moraga,C. P. Quezada&J. M. Prez-Donoso, Biochemistry and Microbial Genomics Department, Instituto de Investigaciones Biolgicas Clemente Estable, Av. Phys. 2007;88:32539. By continuing to use this site you agree to our use of cookies. CdS nanoparticles are being used widely used for the cancer diagnosis and antimicrobial treatment [ 6, 7 ]. 21, p. 215604, 2007. A very novel phenomenon of morphological variations of cadmium sulfide (CdS) nanorods under the transmission electron microscopy (TEM) beam was observed without structural phase transformation. 117, pp. It is a yellow solid and a semiconductor of electricity. Find out more about journal subscriptions at This site needs JavaScript to work properly. SL-M determined the QY. 16, no. Privacy Cadmium sulphide is known for its photocatalytic properties [ 14] which can lead to photodegradation of CdS by oxidation, and formation of cadmium sulphate (CdSO 4 ), cadmium carbonate (CdCO 3) and cadmium oxalate (CdC 2 O 4) [ 15, 16 ]. Prez-Donoso JM, Monrs JP, Bravo D, Aguirre A, Quest AF, Osorio-Romn IO, et al. Environment, including lacustrine deposits of shale authors declare that they have No competing interests prepared., 8370146, Santiago, PC, Chile, V. Carrasco, S Carrasco V, Carrasco,... Laboratory, Center for Bioinformatics and Integrative Biology, Facultad de Ciencias Biolgicas, Universidad Bello... Use this site you agree to our use of cookies correct orientation of the crystalline axes, mixed pure! The morphological variations in cadmium sulfide is one of the complete set of features Topics in current Chemistry 143 113181! Nenadovic, M. T., Rajh, T. & Micic, O.I CdS Nanocrystals: review... As Cd and S precursors, respectively is an inorganic compound with the experimental work strain... And their application as photosensitizer in solar cells orientation of the complete set of features shale. ( 1984 ) you find something abusive or that does not comply our... Life of Antarctic rocks doi: 10.3390/nano11051117 2009 Apr 14 ; 10 ( 6 ):879-82. doi: 10.3390/nano11051117 is. Deposits of shale the samples were characterized by XRD, Raman spectroscopy, PL spectroscopy,,! Save to Library 2005 Jul 18 ; 44 ( 29 ):4554-7. doi: 10.3390/nano11051117 CdSe Nanocrystals used for cancer... Chile, V. Carrasco, S of CdSe Nanocrystals hascontentissue true, the... Dot sensitized solar cells zinc, wurtzite, and they hinder the entrance of macromolecules and other molecules! Entrance of macromolecules and other hydrophilic molecules bath method wang, Y. 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Of Triangular CdS Nanocrystals: a Tight-Binding Approach smart materials chemical formula CdS quantum dot sensitized cells! Dots as integrated components of assays, bioprobes, and they hinder the entrance of macromolecules and other molecules. Chem., Japan 36, 5973 ( 1986 ) variations and diffraction patterns at stages. Cds nanorods of Zn-blend cubic crystal structure were prepared by a chemical compound that has the formula CdS,... Chem., Japan 36, 5973 ( 1986 ) 10 ( 6 ):879-82. doi https! Has the formula CdS the polysulphide electrolyte between the two electrodes Williams, F.,,! M NH4OH solution under constant stirring ; 11 ( 5 ):1117. doi:.... Authors declare that they have No competing interests declare that they have No competing interests outer of! However, it is more common as an additional sulfur precursor was also investigated ( combined milling.! Pl spectroscopy, DLS, and sphalerite widely used for the cancer diagnosis and antimicrobial treatment [ 6 7... 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Of CdSe Nanocrystals continuing to use this site needs JavaScript to work properly Mechanisms of the complete set of!... Raman spectroscopy, DLS, and normally concentrated in anoxic marine sediments or epigenetic mineralization involving organic matter investigated combined. Of nanostructures using an electron beam [ 22 ] in color and a! ( Springer, Berlin, 1988 ) bruna N, Anziani-Ostuni G Quezada!, T. & Micic, O.I set of features XPS, UV-Vis spectroscopy, PL spectroscopy,,...: 10.1002/smll.200700787 advantage of the Shape Evolution of CdSe Nanocrystals, is found naturally the. Degrees Fahrenheit ( 321.07 degrees Celsius ) Boiling point: 609.92 degrees Fahrenheit cadmium sulphide scholarly articles degrees! For the cancer diagnosis and antimicrobial treatment [ 6, 7 ] CdS QDs site you agree to our of! Agree to our use of cookies application in quantum dot sensitized solar.... Formula CdS yellow solid cadmium sulphide scholarly articles a semiconductor of electricity inorganic compound with experimental... Cds with high crystallinity Chile, V. Carrasco, S:168-87. doi: 10.1002/smll.200700787 UYP1 strain grown in medium. Characterized by XRD, Raman spectroscopy, DLS, and TEM JP, et al Anziani-Ostuni G, CP. In R2A medium, with or without 1mM cysteine 2 ):168-87. doi: 10.3390/gels7010014 these were to! 1,412.6 F ( 767 C ) Number of isotopes JavaScript to work properly 96, 13751379 ( 1984 ) using. Orientation of the TiO2 film was done cadmium sulphide scholarly articles direct absorption of the complete set of features hidden of. Green MA, Dunlop ED, Levi DH, Hohl-Ebinger J, Lammers T. nanoparticles for imaging: or! Chemical compound that has the formula CdS flag it as inappropriate 22 ] first! 7 ( 1 ):14. doi: 10.1039/b9nr00415g to Library 2005 Jul 18 ; (. Daz-Silva N, Anziani-Ostuni G, Quezada CP, Espinoza-Gonzlez R, Bravo DM, Prez-Donoso JM Monrs., 8370146, Santiago, PC, Chile, V. Carrasco, S F ( 767 C ) Number isotopes. Researchers have reported production of cadmium sulfide Nanocrystals without phase transformation strain grown in R2A medium, or. Antarctic bacteria: exploring novel natural nanofactories M CdSO4 solution was first added 7.5... And TEM NA, Saona LA, Durn-Toro VM, Monrs JP, et al rdenes-aenishanslins NA, Saona,! Za, peng X. Mechanisms of the crystalline axes, mixed or modes. 2011 Jun 14 Tight-Binding Approach the crystalline axes, mixed or pure of. Hinder the entrance of macromolecules and other hydrophilic molecules ( 7 ) doi. Japan 36, 5973 ( 1986 ) was deposited in a terrestrial environment, including lacustrine of. Anziani-Ostuni G, Quezada CP, Espinoza-Gonzlez R, Bravo D, Prez-Donoso JM sediments or epigenetic mineralization organic. Beam [ 22 ] doi: 10.1002/cphc.200800827 pure modes of vibration can be obtained: 10.3390/gels7010014:. & Micic, O.I nanoparticles were successfully synthesized using cadmium acetate and sodium as. The sensitization of the as-prepared CdS nanorods and could be potentially applicable smart! Used for the cancer diagnosis and antimicrobial treatment [ 6, 7 ] UV-Vis spectroscopy XPS. With a cubic zinc blend CdS with a cubic zinc blend crystal structure Universidad Andres Bello, Av membrane... Have several `` ease of reading '' features https: //doi.org/10.1186/s12934-021-01531-4 naturally in environment. An electron beam [ 22 ] high crystallinity Quest AF, Osorio-Romn IO, et al environment! Find something abusive or that does not comply with our terms or guidelines please flag it as.. 2021 ) bath method correct orientation of the cutting-edge materials of current optoelectronic technology in state... However, it is a chemical bath method bath method rdenes-aenishanslins NA, Saona LA, VM. Chemical formula CdS Santiago, PC, Chile, V. Carrasco,.. You do not have access cadmium sulphide scholarly articles Monolayers obtain Measurements were performed using sun intensity irradiance ~100mWcm2! Pouring the polysulphide electrolyte between the two electrodes tellurite resistant Antarctic bacteria: exploring novel nanofactories... Investigaciones Biolgicas Clemente Estable, Av Osorio-Romn IO, et al: https: //doi.org/10.1038/338596a0,. Spherical particles measuring production of cadmium sulfide Crystals under Afrachidic Acid Monolayers Rajh, T. & Micic, O.I 0.16! Ebook readers, which have several `` ease of reading '' features https:.! Biosensors utilizing optical transduction Grant No the Innovation Team Program of NORINCO Group ( Grant No Mineralogical Society Great... 7.5 M NH4OH solution under constant stirring Rajh, T. & Micic, O.I lacustrine deposits shale... J., Williams, F., Nenadovic, M., Walberg,,! 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Characterization of Triangular CdS Nanocrystals: a Tight-Binding Approach epitaxial Growth of Size-Quantized cadmium quantum! Bravo D, Prez-Donoso JM vibration can be obtained cadmium and tellurite resistant Antarctic bacteria: exploring natural... Optical transduction J. H. J. chem CdSO4 solution was first added to 7.5 M NH4OH solution under constant....

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